An ultrahigh vacuum surface analysis instrument incorporating a Fourier transform mass spectrometer and a Fourier transform infrared spectrometer

被引:11
作者
Abdelrehim, IM [1 ]
Thornburg, NA [1 ]
Land, DP [1 ]
机构
[1] Univ Calif Davis, Dept Chem, Davis, CA 95616 USA
关键词
D O I
10.1063/1.1148434
中图分类号
TH7 [仪器、仪表];
学科分类号
0804 ; 080401 ; 081102 ;
摘要
An ultrahigh vacuum chamber equipped with Fourier transform reflection absorption infrared spectroscopy, Fourier transform mass spectrometry, laser-induced thermal desorption, Auger electron spectroscopy, and low energy electron diffraction is described. The marriage of the various techniques has]ed to novel designs for sample manipulation and incorporation of the instrumentation. A new ion deflection technique is also described. Some results from studies of hydrocarbon reactions on Pd(111) surfaces, such as desorption kinetics for propene and the kinetics and mechanisms of acetylene cyclization to benzene and thiophene, are discussed, as are analyses of oxidized Ti foils exposed to the ambient environment. The performance of this instrument is thus evaluated. (C) 1997 American Institute of Physics.
引用
收藏
页码:4572 / 4582
页数:11
相关论文
共 62 条
[1]   Coverage effects on the kinetics of benzene formation from acetylene on Pd(111): A laser-induced thermal desorption Fourier transform mass spectrometry investigation [J].
Abdelrehim, IM ;
Caldwell, TE ;
Land, DP .
JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (24) :10265-10268
[2]   BENZENE AND THIOPHENE FORMATION FROM ACETYLENE ON SULFIDED PD(111) STUDIED BY LITD FTMS [J].
ABDELREHIM, IM ;
THORNBURG, NA ;
SLOAN, JT ;
LAND, DP .
SURFACE SCIENCE, 1993, 298 (01) :L169-L172
[3]   KINETICS AND MECHANISM OF BENZENE FORMATION FROM ACETYLENE ON PD(111) STUDIED BY LASER-INDUCED THERMAL-DESORPTION FOURIER-TRANSFORM MASS-SPECTROMETRY [J].
ABDELREHIM, IM ;
THORNBURG, NA ;
SLOAN, JT ;
CALDWELL, TE ;
LAND, DP .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (37) :9509-9514
[4]  
[Anonymous], 1978, EPA NIH MASS SPECTRA
[5]  
Benninghoven A., 1987, SECONDARY ION MASS S
[6]   SCANNING TUNNELING MICROSCOPY - FROM BIRTH TO ADOLESCENCE [J].
BINNIG, G ;
ROHRER, H .
REVIEWS OF MODERN PHYSICS, 1987, 59 (03) :615-625
[7]   VIBRATIONAL SPECTROSCOPY OF ADSORBED ATOMS AND MOLECULES [J].
BRADSHAW, AM .
APPLICATIONS OF SURFACE SCIENCE, 1982, 11-2 (JUL) :712-729
[8]   CHEMISORPTION OF CARBON-MONOXIDE ON PALLADIUM SINGLE-CRYSTAL SURFACES - IR SPECTROSCOPIC EVIDENCE FOR LOCALIZED SITE ADSORPTION [J].
BRADSHAW, AM ;
HOFFMANN, FM .
SURFACE SCIENCE, 1978, 72 (03) :513-535
[9]   Thiophene decomposition on Pd(111) forms S and C-4 species: A laser-induced thermal desorption/Fourier transform mass spectrometry study [J].
Caldwell, TE ;
Abdelrehim, IM ;
Land, DP .
SURFACE SCIENCE, 1996, 367 (01) :L26-L31
[10]   FREQUENCY-SWEEP FOURIER-TRANSFORM ION-CYCLOTRON RESONANCE SPECTROSCOPY [J].
COMISARO.MB ;
MARSHALL, AG .
CHEMICAL PHYSICS LETTERS, 1974, 26 (04) :489-490