Selective oxidation of methanol to dimethoxymethane under mild conditions over V2O5/TiO2 with enhanced surface acidity

被引：82

作者：

Fu, Yuchuan ^{[1
]}

Shen, Jianyi ^{[1
]}

机构：

[1] Nanjing Univ, Sch Chem & Chem Engn, Lab Mesoscop Chem, Nanjing 210093, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2007年 / 21期

关键词：

D O I：

10.1039/b618898b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Dimethoxymethane was synthesized from the direct oxidation of methanol with high conversion and selectivity over specially designed bifunctional V2O5/TiO2 catalysts with redox and enhanced acidic character, in which the surface acidity played an essential role for inhibiting the formation of formaldehyde through the enhanced condensation reaction of formaldehyde with methanol to produce dimethoxymethane.

引用

页码：2172 / 2174

页数：3

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