Spectrophotometric study of the solubility and the protolytic properties of 1-(2-pyridylazo)-2-naphthol in different ethanol-water solutions

被引：17

作者：

Coo, LD ^{[1
]}

Cardwell, TJ ^{[1
]}

Cattrall, RW ^{[1
]}

Kolev, SD ^{[1
]}

机构：

[1] La Trobe Univ, Sch Chem, Ctr Sci Instrumentat, Bundoora, Vic 3083, Australia

来源：

ANALYTICA CHIMICA ACTA | 1998年 / 360卷 / 1-3期

基金：

澳大利亚研究理事会;

关键词：

PAN; solubility; protolytic constants; acidity; basicity; ethanol-water;

D O I：

10.1016/S0003-2670(97)00712-5

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The solubility and the protolytic constants of 1-(2-pyridylazo)-2-naphthol (PAN) have been accurately determined at temperatures between 20.0 and 30.0 degrees C in ethanol-water solutions with ethanol concentrations ranging from 10.0% to 95.0% (v/v). The measurement of the protolytic constants is based on the spectrophotometric determination of the concentrations of the corresponding conjugate acid-base pairs in ethanol-water solutions containing PAN and hydrochloric acid or sodium hydroxide. The traditionally used pH measurements in such studies in non-aqueous solutions are thus avoided. The solubility and the protolytic constants of PAN in pure water have been calculated by extrapolating the ethanol-water results to pure water where PAN is practically insoluble. The determination of the thermodynamic data mentioned above is necessary for elucidating the interactions of PAN with various metal ions in solutions and in cation-exchange membranes (e.g., Nafion(R)) used as PAN-based optodes. (C) 1998 Elsevier Science B.V.

引用

页码：153 / 159

页数：7

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