A simple, one-step procedure for the formation of chiral metallamacrocycles

被引：43

作者：

Campbell, K

Johnson, CA

McDonald, R

Ferguson, MJ

Haley, MM

Tykwinski, RR ^{[1
]}

机构：

[1] Univ Alberta, Dept Chem, X Ray Crystallog Lab, Edmonton, AB T6G 2G2, Canada

[2] Univ Oregon, Dept Chem, Eugene, OR 97403 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 44期

关键词：

chirality; macrocycles; P ligands; platinum; supramolecular chemistry;

D O I：

10.1002/anie.200461139

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A twist in the final stage: Chiral, conjugated metallamacrocycles can be formed in excellent yield in a single step from achiral precursors by ligand exchange between (R,R)- or (S,S)-chiraphos and trans platinum acetylide complexes (see scheme).

引用

页码：5967 / 5971

页数：5

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