Stereoselective synthesis of electrophilic spirocyclopropanes in ionic liquids

被引：38

作者：

Calò, V ^{[1
]}

Nacci, A ^{[1
]}

Lopez, L ^{[1
]}

Lerario, VL ^{[1
]}

机构：

[1] Univ Bari, Dipartmento Chim, Ctr CNR MISO, I-70126 Bari, Italy

来源：

TETRAHEDRON LETTERS | 2000年 / 41卷 / 46期

关键词：

cyclopropanation; stereocontrol; ionic liquids; benzothiazole; sulfides;

D O I：

10.1016/S0040-4039(00)01593-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reaction of beta -oxosulfides of benzothiazole with Michael accepters, in liquid tetrabutylammonium bromide and sodium bicarbonate as base, allows a stereoselective synthesis of spirocyclopropanes. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：8977 / 8980

页数：4

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