A new approach for the fabrication of strongly heterogeneous mixed self-assembled monolayers

被引：26

作者：

Ballav, Nirmalya

Weidner, Tobias

Rossler, Katrin

Lang, Heinrich

Zharnikov, Michael ^{[1
]}

机构：

[1] Univ Heidelberg, D-69120 Heidelberg, Germany

[2] Tech Univ Chemnitz, Inst Chem, Lehrstuhl Anorgan Chem, D-09111 Chemnitz, Germany

来源：

CHEMPHYSCHEM | 2007年 / 8卷 / 06期

关键词：

electron irradiation; exchange reactions; molecular devices; monolayers; self-assembly;

D O I：

10.1002/cphc.200700120

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

(Figure Presented) Thiol exchange: A new approach to fabricate strongly heterogeneous mixed self-assembled monolayers (SAMs) is presented. The mixing occurs by the exchange reaction between a one-component SAM and a suitable second component. The exchange reaction is promoted and precisely tuned by preliminary electron irradiation. As a validity test, mixed aliphatic-aromatic SAMs and templates comprised of active molecules and matrix molecules (see picture) are prepared. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：819 / 822

页数：4

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