Interfacial effects on the reinforcement properties of polymer-organoclay nanocomposites

被引：321

作者：

Shi, HZ

Lan, T

Pinnavaia, TJ

机构：

[1] MICHIGAN STATE UNIV,DEPT CHEM,E LANSING,MI 48824

[2] MICHIGAN STATE UNIV,CTR FUNDAMENTAL MAT RES,E LANSING,MI 48824

来源：

CHEMISTRY OF MATERIALS | 1996年 / 8卷 / 08期

关键词：

D O I：

10.1021/cm960227m

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Interfacial effects play a major role in the formation of organic polymer-smectite clay nanocomposites. As little 2 mol % Na+ cations on the exchange sites of a short-chain alkylammonium smectite clay completely inhibits exfoliation of the silicate nanolayers in an epoxy matrix. Nanolayer Pinning by Na(H2O)(n)(+) Ion [GRAPHICS] 00 nm) top layer (shown here) of zeolite L crystals.

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页码：1584 / &

页数：5

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