Arylarnine-substituted hexa-peri-hexabenzocoronenes:: Facile synthesis and their potential applications as "coaxial" hole-transport materials

被引：79

作者：

Wu, JS

Baumgarten, M

Debije, MG

Warman, JM

Müllen, K

机构：

[1] Max Planck Inst Polymer Res, D-55128 Mainz, Germany

[2] Delft Univ Technol, Interfac Reactor Inst, NL-2629 JB Delft, Netherlands

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 40期

关键词：

arylamines; electron transfer; hole transport; liquid crystals; pi interactions;

D O I：

10.1002/anie.200460174

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The hole story: using a new synthetic concept the title hexa-peri-hexabenzocoronenes (HBCs) were synthesized with high atom economy. The coaxial arrangement of the HBCs and arylamines allowed a "double- cable" hole transport (see picture), that is, transport through the central core (white) and the outer shell (green).

引用

收藏

页码：5331 / 5335

页数：5

相关论文

共 36 条

[1] Solid-state dye-sensitized mesoporous TiO2 solar cells with high photon-to-electron conversion efficiencies [J].

Bach, U ;

Lupo, D ;

Comte, P ;

Moser, JE ;

Weissörtel, F ;

Salbeck, J ;

Spreitzer, H ;

Grätzel, M .

NATURE, 1998, 395 (6702) :583-585

[2] Printable organic and polymeric semiconducting materials and devices [J].

Bao, ZN ;

Rogers, JA ;

Katz, HE .

JOURNAL OF MATERIALS CHEMISTRY, 1999, 9 (09) :1895-1904

[3] ORGANIC MIXED-VALENCE SYSTEMS - INTERVALENCE TRANSITION IN PARTLY OXIDIZED AROMATIC POLYAMINES - ELECTROCHEMICAL AND OPTICAL STUDIES [J].

BONVOISIN, J ;

LAUNAY, JP ;

VANDERAUWERAER, M ;

DESCHRYVER, FC .

JOURNAL OF PHYSICAL CHEMISTRY, 1994, 98 (19) :5052-5057

[4] CHARGE TRANSPORT IN DISORDERED MOLECULAR-SOLIDS [J].

BORSENBERGER, PM ;

PAUTMEIER, L ;

BASSLER, H .

JOURNAL OF CHEMICAL PHYSICS, 1991, 94 (08) :5447-5454

[5] HOLE TRANSPORT IN 1,1-BIS(DI-4-TOLYLAMINOPHENYL)CYCLOHEXANE [J].

BORSENBERGER, PM ;

PAUTMEIER, L ;

RICHERT, R ;

BASSLER, H .

JOURNAL OF CHEMICAL PHYSICS, 1991, 94 (12) :8276-8281

[6] Charge-transfer transitions in triarylamine mixed-valence systems:: A joint density functional theory and vibronic coupling study [J].

Coropceanu, V ;

Malagoli, M ;

André, JM ;

Brédas, JL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (35) :10519-10530

[7] Structure and dynamics in columnar discotic materials:: A combined X-ray and solid-state NMR study of hexabenzocoronene derivatives [J].

Fischbach, I ;

Pakula, T ;

Minkin, P ;

Fechtenkötter, A ;

Müllen, K ;

Spiess, HW ;

Saalwächter, K .

JOURNAL OF PHYSICAL CHEMISTRY B, 2002, 106 (25) :6408-6418

[8] Electroluminescence in conjugated polymers [J].

Friend, RH ;

Gymer, RW ;

Holmes, AB ;

Burroughes, JH ;

Marks, RN ;

Taliani, C ;

Bradley, DDC ;

Dos Santos, DA ;

Brédas, JL ;

Lögdlund, M ;

Salaneck, WR .

NATURE, 1999, 397 (6715) :121-128

[9] Room-temperature palladium-catalyzed amination of aryl bromides and chlorides and extended scope of aromatic C-N bond formation with a commercial ligand [J].

Hartwig, JF ;

Kawatsura, M ;

Hauck, SI ;

Shaughnessy, KH ;

Alcazar-Roman, LM .

JOURNAL OF ORGANIC CHEMISTRY, 1999, 64 (15) :5575-5580

[10] SYNTHESIS OF A HEXAALKYNYLHEXAPHENYLBENZENE [J].

HYATT, JA .

ORGANIC PREPARATIONS AND PROCEDURES INTERNATIONAL, 1991, 23 (04) :460-463

← 1 2 3 4 →