Diels-Alder reactions in water

被引：198

作者：

Otto, S ^{[1
]}

Engberts, JBFN ^{[1
]}

机构：

[1] Univ Groningen, Stratingh Inst, Dept Organ & Mol Inorgan Chem, NL-9747 AG Groningen, Netherlands

来源：

PURE AND APPLIED CHEMISTRY | 2000年 / 72卷 / 07期

关键词：

D O I：

10.1351/pac200072071365

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This review illustrates how water, as an environmentally friendly solvent, can have significant additional benefits when it is used as a solvent for the Diels-Alder reaction. The mechanism by which the unique properties of water enhance the rate and selectivity are discussed. Also, possibilities for the achievement of further increases in rate and enantioselectivity of aqueous Diels-Alder reactions through Lewis-acid and micellar catalysis are reviewed.

引用

页码：1365 / 1372

页数：8

共 72 条

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