Influence of synthesis parameters on the growth of US nanoparticles in colloidal solution and determination of growth kinetics using Karhunen-Loeve decomposition

被引：15

作者：

Barglik-Chory, C

Münster, AF

Strohm, H

Remenyi, C

Müller, G

机构：

[1] Univ Wurzburg, Lehrstuhl Silicatchem, D-97070 Wurzburg, Germany

[2] Univ Wurzburg, Inst Phys Chem, D-97074 Wurzburg, Germany

来源：

CHEMICAL PHYSICS LETTERS | 2003年 / 374卷 / 3-4期

关键词：

D O I：

10.1016/S0009-2614(03)00706-1

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The growth of US nanoparticles during aging at ambient temperature is investigated with respect to the type of stabilizer, the concentration of the colloidal solution, and the molar ratio of sulfide to cadmium. The UV/Vis absorption spectra recorded within a period of seven days are analyzed by Karhunen-Loeve decomposition. It revealed a single process with first-order decomposition kinetics for each of the measured time series, and the respective rate constants are calculated. An explanation describing possible mechanisms for the observed ripening of the colloids is given. (C) 2003 Elsevier Science B.V. All rights reserved.

引用

页码：319 / 325

页数：7

共 26 条

[1] EVOLUTION OF CLUSTER SIZE DISTRIBUTION IN NUCLEATION AND GROWTH-PROCESSES [J].