X-ray absorption Spectroscopy of low temperature fuel cell catalysts

被引：247

作者：

Russell, AE ^{[1
]}

Rose, A ^{[1
]}

机构：

[1] Univ Southampton, Sch Chem, Southampton SO17 1BJ, Hants, England

来源：

CHEMICAL REVIEWS | 2004年 / 104卷 / 10期

关键词：

D O I：

10.1021/cr020708r

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Over the years, XAS has been successfully employed in the characterization of a number of catalysis used in low temperature fuel cells. Analysis of the XANES region enabled determination of the oxidation state of metal atoms in the catalyst or, in the case of Pt, the d band vacancy per atom, while analysis of the EXAFS proved to be a valuable structural tool. However, the key advantage of XAS is that it can be used in situ, in a flooded half-cell or true fuel cell environment.

引用

页码：4613 / 4635

页数：23

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