Transition-metal-containing chiral bidentate ligands for enantioselective catalysis: non-metallocene architectural units come of age

被引：74

作者：

Delacroix, O ^{[1
]}

Gladysz, JA ^{[1
]}

机构：

[1] Univ Erlangen Nurnberg, Inst Organ Chem, D-91054 Erlangen, Germany

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 06期

关键词：

D O I：

10.1039/b207963c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Structural and electronic properties associated with donor ligands that contain 'spectator' transition-metal fragments are analyzed. The current status of such non-ferrocenyl chiral bidentate ligands is reviewed from the standpoint of synthesis, applications in metal-catalyzed enantioselective reactions, and future directions.

引用

页码：665 / 675

页数：11

共 101 条

[1] Comparing chiral ferrocenyl and ruthenocenyl ligands: How subtle structural changes influence their performance in asymmetric catalysis [J].

Abbenhuis, HCL ;

Burckhardt, U ;

Gramlich, V ;

Martelletti, A ;

Spencer, J ;

Steiner, I ;

Togni, A .

ORGANOMETALLICS, 1996, 15 (06) :1614-1621

[2] A new family of chiral chelating diamines with transition-metal stereocenters:: Synthesis, structure, and reactivity of the enantiomerically pure dirhenium-substituted 1,2-diamine (η5-C5H5)Re(NO)(PPh3) (CH2N(CH3)CH2CH2(H3C)NCH2)(Ph3P)(ON)Re(η5-C5H5) [J].

Alvey, LJ ;

Delacroix, O ;

Wallner, C ;

Meyer, O ;

Hampel, F ;

Szafert, S ;

Lis, T ;

Gladysz, JA .

ORGANOMETALLICS, 2001, 20 (14) :3087-3096

[3]

[Anonymous], COMPREHENSIVE ASYMME

[4]

[Anonymous], INORG SYNTH

[5]

[Anonymous], ANGEW CHEM

[6]

Bergner EJ, 2000, EUR J ORG CHEM, V2000, P419, DOI 10.1002/(SICI)1099-0690(200002)2000:3<419::AID-EJOC419>3.0.CO

[7]

2-N

[8] Solvias Josiphos ligands: from discovery to technical applications [J].

Blaser, HU ;

Brieden, W ;

Pugin, B ;

Spindler, F ;

Studer, M ;

Togni, A .

TOPICS IN CATALYSIS, 2002, 19 (01) :3-16

[9] New chiral tricarbonyl(η6-arene)chromium(0) complexes:: synthesis and preliminary application in asymmetric catalysis [J].

Bolm, C ;

Muñiz, K ;

Ganter, C .

NEW JOURNAL OF CHEMISTRY, 1998, 22 (12) :1371-1376

[10] Planar chiral arene chromium(0) complexes:: potential ligands for asymmetric catalysis [J].

Bolm, C ;

Muñiz, K .

CHEMICAL SOCIETY REVIEWS, 1999, 28 (01) :51-59

← 1 2 3 4 5 6 7 8 9 10 →