Gel template leaching: An approach to functional nanoporous membranes

被引：39

作者：

Gankema, H

Hempenius, MA

Moller, M

Johansson, G

Percec, V

机构：

[1] UNIV ULM,DEPT ORGAN CHEM MACROMOLEC CHEM 3,D-89069 ULM,GERMANY

[2] TWENTE UNIV TECHNOL,DEPT CHEM TECHNOL,7500 AE ENSCHEDE,NETHERLANDS

[3] CASE WESTERN RESERVE UNIV,DEPT MACROMOLEC SCI,CLEVELAND,OH 44106

来源：

MACROMOLECULAR SYMPOSIA | 1996年 / 102卷

关键词：

D O I：

10.1002/masy.19961020145

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A novel preparation method for nanoporous structures, denoted ''Gel Template Leaching'', is described. The approach is based on the gelation of solutions containing two low molecular weight compounds of which one is crystallizable and the other curable. Gelation of the solute upon cooling followed by curing of the solvent below the gelation temperature lead to the formation of a semi-IPN consisting of a reversibly and a covalently crosslinked network. After leaching of the solute (the template) a well-defined nanoporous architecture was formed. Functional pores could be obtained after charging the pore walls with ionic sites.

引用

页码：381 / 390

页数：10

共 15 条

[1] CUPERUS FP, 1990, THESIS TWENTE U ENSC
[2] GANKEMA H, 1994, RECL TRAV CHIM PAY B, V113, P241
[3] GANKEMA H, UNPUB PHASE BEHAVIOU
[4] GANKEMA H, UNPUB MORPHOLOGY DOB
[5] GANKERNA H, UNPUB GEL TEMPLATE L
[6] Kesting R.E., 1985, SYNTHETIC POLYM MEMB, V2nd
[7] KORYTA J, 1992, PRINCIPLES ELECTROCH
[8] MICROPOROUS MEMBRANE FORMATION VIA THERMALLY INDUCED PHASE-SEPARATION .1. SOLID LIQUID-PHASE SEPARATION
LLOYD, DR
KINZER, KE
TSENG, HS
[J]. JOURNAL OF MEMBRANE SCIENCE, 1990, 52 (03) : 239 - 261
[9] NANOMATERIALS - A MEMBRANE-BASED SYNTHETIC APPROACH
MARTIN, CR
[J]. SCIENCE, 1994, 266 (5193) : 1961 - 1966
[10] Mulder M., 2012, BASIC PRINCIPLES MEM

← 1 2 →