Synthesis of bridged soluble phthalocyaninatoruthenium complexes

被引：13

作者：

Hanack, M ^{[1
]}

Hees, M ^{[1
]}

Witke, E ^{[1
]}

机构：

[1] Univ Tubingen, Inst Organ Chem, D-72076 Tubingen, Germany

来源：

NEW JOURNAL OF CHEMISTRY | 1998年 / 22卷 / 02期

关键词：

D O I：

10.1039/a708321a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis and characterization of hitherto unknown soluble octasubstituted ruthenium phthalocyanines R8PcRu(R = C5H11O) by vacuum thermolysis of their bisaxial adducts with 3-chloropyridine is described. R8PcRu (R = C5H11O, 2-Et-hexO) was reacted with 1,4-diisocyano-2,3,5,6-tetramethylbenzene (me(4)dib) and 1,4-diisocyanobenzene (dib) to afford the oligomers [R8PcRu(me(4)dib)](n) (R = C5H11O, 2-Et-hexO) and [R8PcRu(dib)](n) (R = C5H11O), which were characterized by spectroscopic methods.

引用

页码：169 / 172

页数：4

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