Ion exchange equilibria between glass and molten salts

被引：28

作者：

Araujo, RJ ^{[1
]}

Likitvanichkul, S ^{[1
]}

Thibault, Y ^{[1
]}

Allan, DC ^{[1
]}

机构：

[1] Corning Inc, Fundamental Res, Corning, NY 14831 USA

来源：

JOURNAL OF NON-CRYSTALLINE SOLIDS | 2003年 / 318卷 / 03期

关键词：

D O I：

10.1016/S0022-3093(02)01888-4

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

It is shown that interaction between the ions undergoing ion exchange leads to a sigmoidal equilibrium curve. A negative interaction in the glass causes the ratio of concentration of the two ions to be more nearly equal to unity in the glass than it is in the molten salt. It is further shown that the Rothmund-Kornfeld parameter is a measure of the non-ideality of the system. A value of the parameter greater than unity indicates a negative interaction energy. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：262 / 267

页数：6

共 5 条

[1] Potential functions in chemical thermodynamics [J].

Araujo, R .

JOURNAL OF CHEMICAL EDUCATION, 1998, 75 (11) :1490-1493

[2]

BORRELLI NF, 1999, MICROOPTICS TECHNOLO, P72

[3] ION-EXCHANGE EQUILIBRIA BETWEEN GLASS AND MOLTEN SALTS [J].

GARFINKE.HM .

JOURNAL OF PHYSICAL CHEMISTRY, 1968, 72 (12) :4175-&

[4]

HILL TL, 1960, STATISTICAL THERMODY, P235

[5] Base replacement in permutite. I [J].

Rothmund, V ;

Kornfeld, G .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1918, 103 (03) :129-163

← 1 →