A tailored organometallic gelator with enhanced amphiphilic character and structural diversity of gelation

被引：68

作者：

Klawonn, Thorsten

Gansaeuer, Andreas

Winkler, Iris

Lauterbach, Thorsten

Franke, Dieter

Nolte, Roeland J. M.

Feiters, Martin C.

Boerner, Hans

Hentschel, Jens

Doetz, Karl Heinz

机构：

[1] Kekule Inst Organ chem & Biochem, D-53121 Bonn, Germany

[2] Radboud Univ Nijmegen, Inst Mol & Mat, NL-6525 ED Nijmegen, Netherlands

[3] Max Planck Inst Colloids & Interfaces, D-14424 Potsdam, Germany

来源：

CHEMICAL COMMUNICATIONS | 2007年 / 19期

关键词：

D O I：

10.1039/b701565h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A cholesterol-appended titanocene gelator was synthesised which forms twisted fibers able to gelate a variety of solvents of different polarity as demonstrated by spectroscopic and microscopic techniques.

引用

页码：1894 / 1895

页数：2

共 20 条

[1] A NOVEL SMALL MOLECULAR LUMINESCENT GELLING AGENT FOR ALCOHOLS [J].

BROTIN, T ;

UTERMOHLEN, R ;

FAGES, F ;

BOUASLAURENT, H ;

DESVERGNE, JP .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (06) :416-418

[2] A metal-carbene carbohydrate amphiphile as a low-molecular-mass organometallic gelator [J].

Bühler, G ;

Feiters, MC ;

Nolte, RJM ;

Dötz, KH .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (22) :2494-2497

[3]

CregoCalama M, 2006, TOP CURR CHEM, V265, P1

[4] Water gelation by small organic molecules [J].

Estroff, LA ;

Hamilton, AD .

CHEMICAL REVIEWS, 2004, 104 (03) :1201-1217

[5] A modular and efficient synthesis of functional titanocenes [J].

Gansäuer, A ;

Franke, D ;

Lauterbach, T ;

Nieger, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (33) :11622-11623

[6] Molecular organogels. Soft matter comprised of low-molecular-mass organic gelators and organic liquids [J].

George, Mathew ;

Weiss, Richard G. .

ACCOUNTS OF CHEMICAL RESEARCH, 2006, 39 (08) :489-497

[7]

Gottarelli G, 2006, MOLECULAR GELS: MATERIALS WITH SELF-ASSEMBLED FIBRILLAR NETWORKS, P431, DOI 10.1007/1-4020-3689-2_14

[8] Two-component dendritic gel: Effect of stereochemistry on the supramolecular chiral assembly [J].

Hirst, AR ;

Smith, DK ;

Feiters, MC ;

Geurts, HPM .

CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (23) :5901-5910

[9] NOVEL FAMILY OF GELATORS OF ORGANIC FLUIDS AND THE STRUCTURE OF THEIR GELS [J].

LIN, Y ;

KACHAR, B ;

WEISS, RG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (15) :5542-5551

[10] REDOX-SWITCHED MOLECULAR AGGREGATES - THE 1ST EXAMPLE OF VESICLE FORMATION FROM HYDROPHOBIC FERROCENE DERIVATIVES [J].

MEDINA, JC ;

GAY, I ;

CHEN, ZH ;

ECHEGOYEN, L ;

GOKEL, GW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (01) :365-366

← 1 2 →