Remarkably variable reaction modes of frustrated Lewis pairs with non-conjugated terminal diacetylenes

被引：82

作者：

Chen, Chao ^{[1
]}

Froehlich, Roland ^{[1
]}

Kehr, Gerald ^{[1
]}

Erker, Gerhard ^{[1
]}

机构：

[1] Univ Munster, Inst Organ Chem, D-48149 Munster, Germany

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 20期

关键词：

REDUCTIVE CYCLIZATION; 1,1-ORGANOBORATION; HYDROGEN; CARBOBORATION; CHLOROBORANE; DERIVATIVES; ACTIVATION; 1,6-ENYNES; CHIRALITY;

D O I：

10.1039/b926830h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The frustrated Lewis pair P(o-tolyl)(3)/B(C6F5)(3) reacts with 1,7-octadiyne by acetylene C-C coupling to yield the zwitterionic product 2a. In contrast, the P(o-tolyl)(3)/B(C6F5)(3) Lewis pair reacts with 1,6-heptadiyne by a sequence involving 1,1-carboboration of a terminal acetylene to eventually yield the heterocyclic product 4.

引用

页码：3580 / 3582

页数：3

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