Fabrication of TiO2 porous thin films using peg templates and chemistry of the process

被引：65

作者：

Bu, SJ ^{[1
]}

Jin, ZG ^{[1
]}

Liu, XX ^{[1
]}

Yang, LR ^{[1
]}

Cheng, ZJ ^{[1
]}

机构：

[1] Tianjin Univ, Sch Mat, Minist Educ, Key Lab Adv Ceram & Machining Technol, Tianjin 300072, Peoples R China

来源：

MATERIALS CHEMISTRY AND PHYSICS | 2004年 / 88卷 / 2-3期

关键词：

TiO2 porous thin films; templating; polyethylene glycol; chemical mechanism;

D O I：

10.1016/j.matchemphys.2004.03.033

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Titanate porous films have been deposited on glass slides by a sol-gel dip-coating technology. Tetrabutylorthotitanate and polyethylene glycol (PEG) were used as a precursor and template, respectively. The chemical mechanism of the process is discussed in relation to the sol-gel transition, which provides a possible interpretation to the formation of TiO2 porous films. The morphology of porous TiO2 thin films strongly depends on the amount of water, the types of solvents and complexing agents, and the content and molecular weight of the template. It was shown that the diameter of pores is tunable in the range of 10 nm-1 mum and the maximum of BET specific area of the films is 72 m(2) g(-1). (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：273 / 279

页数：7

共 27 条

[1] PRODUCTION OF STRONTIUM-SUBSTITUTED LANTHANUM MANGANITE PEROVSKITE POWDER BY THE AMORPHOUS CITRATE PROCESS [J].