Oxyfunctionalization of hydrocarbons by in situ formed peracid or by metal assisted aerobic oxidation

被引：18

作者：

Dell'Anna, MM ^{[1
]}

Mastrorilli, P ^{[1
]}

Nobile, CF ^{[1
]}

机构：

[1] Politecn Bari, Ist Chim, CNR, Ctr Metodol Innovat Sintesi Organ, I-70126 Bari, Italy

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1998年 / 130卷 / 1-2期

关键词：

oxidation; alkanes; hydrocarbons; metal beta-diketonates; sacrificial aldehyde; peracid;

D O I：

10.1016/S1381-1169(97)00198-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The oxidation of hydrocarbons such as adamantane, cyclohexane, tetraline and indane has been investigated using the oxygen/3-methylbutanal system in the presence acid in the absence of metal catalyst. The reactivity order reflects the facility of hydrogen abstraction from the substrate. (C) 1998 Elsevier Science B.V.

引用

页码：65 / 71

页数：7

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