A hybrid solid with giant pores prepared by a combination of targeted chemistry, simulation, and powder diffraction

被引：870

作者：

Férey, G ^{[1
]}

Serre, C ^{[1
]}

Mellot-Draznieks, C ^{[1
]}

Millange, F ^{[1
]}

Surblé, S ^{[1
]}

Dutour, J ^{[1
]}

Margiolaki, I ^{[1
]}

机构：

[1] Univ Versailles, CNRS, UMR 8637, Inst Lavoisier, F-78035 Versailles, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 46期

关键词：

microporous materials; molecular modeling; nanoporous materials; organic-inorganic hybrid composites; powder diffraction;

D O I：

10.1002/anie.200460592

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A perfect combination: The association of a chromium(III) trimeric building unit and 1,3,5-benzenetricarboxylate led to the powdered solid MIL-100. Simulations provided a crystal structure solution, which matched the experimental powder XRD pattern. This unique simulation/ diffraction combination allowed the structure determination of a giant-pore solid with a zeotype architecture, built up from hybrid supertetrahedra (see picture). (Figure presented).

引用

页码：6296 / 6301

页数：6

共 39 条

[1]

[Anonymous], 2004, ANGEW CHEM, V116, P6445

[2] Order-disorder in the super-sodalite Zn3Al6(PO4)12, 4tren, 17H2O (MIL-74):: A combined XRD-NMR assessment [J].

Beitone, L ;

Huguenard, C ;

Gansmüller, A ;

Henry, M ;

Taulelle, F ;

Loiseau, T ;

Férey, G .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (30) :9102-9110

[3] A route to high surface area, porosity and inclusion of large molecules in crystals [J].

Chae, HK ;

Siberio-Pérez, DY ;

Kim, J ;

Go, Y ;

Eddaoudi, M ;

Matzger, AJ ;

O'Keeffe, M ;

Yaghi, OM .

NATURE, 2004, 427 (6974) :523-527

[4] A NEW FORM OF FEF3 WITH THE PYROCHLORE STRUCTURE - SOFT CHEMISTRY SYNTHESIS, CRYSTAL-STRUCTURE, THERMAL TRANSITIONS AND STRUCTURAL CORRELATIONS WITH THE OTHER FORMS OF FEF3 [J].

DEPAPE, R ;

FEREY, G .

MATERIALS RESEARCH BULLETIN, 1986, 21 (08) :971-978

[5] Systematic design of pore size and functionality in isoreticular MOFs and their application in methane storage [J].

Eddaoudi, M ;

Kim, J ;

Rosi, N ;

Vodak, D ;

Wachter, J ;

O'Keeffe, M ;

Yaghi, OM .

SCIENCE, 2002, 295 (5554) :469-472

[6] Modular chemistry: Secondary building units as a basis for the design of highly porous and robust metal-organic carboxylate frameworks [J].

Eddaoudi, M ;

Moler, DB ;

Li, HL ;

Chen, BL ;

Reineke, TM ;

O'Keeffe, M ;

Yaghi, OM .

ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (04) :319-330

[7] Building units design and scale chemistry [J].

Férey, G .

JOURNAL OF SOLID STATE CHEMISTRY, 2000, 152 (01) :37-48

[8] Hydrogen adsorption in the nanoporous metal-benzenedicarboxylate M(OH)(O2C-C6H4-CO2) (M = Al3+, Cr3+), MIL-53 [J].

Férey, G ;

Latroche, M ;

Serre, C ;

Millange, F ;

Loiseau, T ;

Percheron-Guégan, A .

CHEMICAL COMMUNICATIONS, 2003, (24) :2976-2977

[9] Porous materials -: Prospects for giant pores [J].

Férey, G ;

Cheetham, AK .

SCIENCE, 1999, 283 (5405) :1125-1126

[10] Real, virtual and not yet discovered porous structures using scale chemistry and/or simulation.: A tribute to Sten!Andersson [J].

Férey, G ;

Mellot-Draznieks, C ;

Loiseau, T .

SOLID STATE SCIENCES, 2003, 5 (01) :79-94

← 1 2 3 4 →