Crystal structure and characterization of organic-inorganic hybridized molecules with molecular zipper structures and two-dimensional grid networks

被引:32
作者
Ang, SG
Sun, BW
机构
[1] Natl Univ Singapore, Fac Sci, Dept Chem, Singapore 117543, Singapore
[2] SE Univ, Dept Chem & Chem Engn, Nanjing 210096, Peoples R China
关键词
D O I
10.1021/cg049847n
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Three succinate-metal coordination polymers have been synthesized and characterized. The structure of Co(dmbpy)(H2O)(2)(C4H4O4) (dmbpy = 4,4'-dimethyl-2,2'-bipyridine, C4H4O4 = succinate; 1) contains zipperlike chains, which are constructed of Co(II), dmbpy, H2O, and bridging succinates. The structure of two isomorphous 2-D compounds, M(dpdo)(H2O)(2)(C4H4O4) (M = Zn (2) or Mn (3), dpdo = 4,4'-dipyridyl N,N'-dioxide), consists of grid networks of succinate-metal chains linked by dpdo.
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页码:383 / 386
页数:4
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