3D-coordination cluster polymers [Ln(H2O)3Re6Te8(CN)6]•nH2O (Ln = La3+, Nd3+):: Direct structural analogy with the mononuclear LnM(CN)6•nH2O family

被引：44

作者：

Artemkina, SB ^{[1
]}

Naumov, NG ^{[1
]}

Virovets, AV ^{[1
]}

Fedorov, VE ^{[1
]}

机构：

[1] Russian Acad Sci, SB, Nikolaev Inst Inorgan Chem, Novosibirsk 630090, Russia

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2005年 / 01期

关键词：

rhenium; cluster compounds; structure elucidation; cyanide ligand; lanthanides;

D O I：

10.1002/ejic.200400139

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Using the hydrothermal method two novel 3D-coordination complexes [Ln(H2O)(3)Re6Te8(CN)(6)].nH(2)O (Ln = La3+, Nd3+) have been synthesised and structurally characterised. For compound [La(H2O)(3)Re6Te8(CN)(6)].4H(2)O (1) the unit cell parameters are: Space group P6(3)/M, a = 9.3060(13), c 20.528(4) Angstrom, V = 1539.6(4) Angstrom(3), R-f = 0.0597. For compound [Nd(H2O)(3)Re6Te8(CN)(6)].H2O (2) the unit cell parameters are: Space group P6(3)/m, a = 9.3030(10), c = 20.222(4) A, V = 1515.7(4) Angstrom(3), R-f = 0.0226. The structures of the cluster compounds are topologically analogous to the mononuclear polymeric complex LaCr(CN)(6).5H(2)O.

引用

页码：142 / 146

页数：5

共 32 条

[1] Expanded Prussian blue analogues incorporating [Re6Se8(CN)6]3-/4- clusters:: Adjusting porosity via charge balance [J].

Bennett, MV ;

Beauvais, LG ;

Shores, MP ;

Long, JR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (33) :8022-8032

[2] Synthesis and structure of a new octahedral molybdenum thiocyanide cluster complex K7[Mo6(μ3-S)8(CN)6] • 8H2O [J].

Brylev, KA ;

Virovets, AV ;

Naumov, NG ;

Mironov, YV ;

Fenske, D ;

Fedorov, VE .

RUSSIAN CHEMICAL BULLETIN, 2001, 50 (07) :1140-1143

[3] STRUCTURE OF LACR(CN)65H2O [J].

DOMMANN, A ;

VETSCH, H ;

HULLIGER, F .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1990, 46 :1994-1996

[4] STRUCTURE OF ERFE(CN)64H2O [J].

DOMMANN, A ;

VETSCH, H ;

HULLIGER, F ;

PETTER, W .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1990, 46 :1992-1994

[5] A PHYSICOCHEMICAL CHARACTERIZATION OF THE CLUSTER-TYPE RHENIUM TELLURIDE RE6TE15 [J].

FEDOROV, VE ;

PODBEREZSKAYA, NV ;

MISCHENKO, AV ;

KHUDOROZKO, GF ;

ASANOV, IP .

MATERIALS RESEARCH BULLETIN, 1986, 21 (11) :1335-1342

[6] Primitive cubic packing of anions in Cs4[Re6Te8(CN)6]•2H2O and Ba2[Re6Te8(CN)6]•12H2O crystals [J].

Imoto, H ;

Naumov, NG ;

Virovets, AV ;

Saito, T ;

Fedorov, VE .

JOURNAL OF STRUCTURAL CHEMISTRY, 1998, 39 (05) :720-727

[7] 3-D coordination network structures constructed from [W6S8(CN)6]6- anions [J].

Jin, S ;

DiSalvo, FJ .

CHEMISTRY OF MATERIALS, 2002, 14 (08) :3448-3457

[8] Novel octahedral tungsten sulfidocyanide cluster anion [W6S8(CN)6]6- [J].

Jin, S ;

DiSalvo, FJ .

CHEMICAL COMMUNICATIONS, 2001, (17) :1586-1587

[9] Crystal structure of the two-dimensional framework [Mn(salen)]4n[Re6Te8(CN)6]n [salen = N,N′-ethylenebis(salicylideneaminato)] [J].

Kim, Y ;

Park, SM ;

Nam, W ;

Kim, SJ .

CHEMICAL COMMUNICATIONS, 2001, (16) :1470-1471

[10]

Mironov YV, 2000, CHEM-EUR J, V6, P1361

← 1 2 3 4 →