Properties and microstructure of NiO/SDC materials for SOFC anode applications

被引:21
作者
Cheng Jigui [1 ]
Deng Liping
Zhang Benrui
Shi Ping
Meng Guangya
机构
[1] Hefei Univ Technol, Dept Mat Sci & Engn, Hefei 230009, Peoples R China
[2] Univ Sci & Technol China, Dept Mat Sci & Engn, Hefei 230026, Peoples R China
关键词
solid oxide fuel cells (SOFC); anodes; NiO/SDC composites; Ni/SDC cermets; physical properties; mechanical properties; microstructure;
D O I
10.1016/S1001-0521(07)60169-7
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
NiO/SDC composites and Ni/SDC cermets for solid oxide fuel cell (SOFC) anode applications were prepared from nickel oxide (NiO) and samaria doped ceria (SDC) powders by the powder metallurgy process. The physical and mechanical properties, as well as the microstructure of the NiO/SDC composites and the Ni/SDC cermets were investigated. It is shown that the sintering temperature of the NiO/SDC composites and NiO content plays an important role in determining the microstructure and properties of the NiO/SDC composites, which, in turn, influences the microstructure, electrical conductivity, and mechanical properties of the Ni/SDC cermets. The present study demonstrated that composition and tprocess parameters must be appropriately selected to optimize the microstructure and the properties of NiO/SDC materials for solid oxide fuel cell applications.
引用
收藏
页码:110 / 117
页数:8
相关论文
共 16 条
[1]   Synthesis and properties of Ni-YSZ cermet: anode material for solid oxide fuel cells [J].
Aruna, ST ;
Muthuraman, M ;
Patil, KC .
SOLID STATE IONICS, 1998, 111 (1-2) :45-51
[2]   Solid oxide electrolyte fuel cell review [J].
Badwal, SPS ;
Foger, K .
CERAMICS INTERNATIONAL, 1996, 22 (03) :257-265
[3]   The development of intermediate-temperature solid oxide fuel cells for the next millennium [J].
Choy, K ;
Bai, W ;
Clarojrochkul, S ;
Steele, BCH .
JOURNAL OF POWER SOURCES, 1998, 71 (1-2) :361-369
[4]   CONDUCTIVITY OF POROUS NI/ZRO2-Y2O3 CERMETS [J].
DEES, DW ;
CLAAR, TD ;
EASLER, TE ;
FEE, DC ;
MRAZEK, FC .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1987, 134 (09) :2141-2146
[5]   The degradation of SOFC electrodes [J].
Hsiao, YC ;
Selman, JR .
SOLID STATE IONICS, 1997, 98 (1-2) :33-38
[6]   Microstructure and anodic properties of Ni/YSZ cermets in solid oxide fuel cells [J].
Lee, CH ;
Lee, CH ;
Lee, HY ;
Oh, SM .
SOLID STATE IONICS, 1997, 98 (1-2) :39-48
[7]   ENHANCED CERIA - A LOW-TEMPERATURE SOFC ELECTROLYTE [J].
MARICLE, DL ;
SWARR, TE ;
KARAVOLIS, S .
SOLID STATE IONICS, 1992, 52 (1-3) :173-182
[8]   Preparation of Ni-YSZ composite materials for solid oxide fuel cell anodes by the gel-precipitation method [J].
Marinsek, M ;
Zupan, K ;
Macek, J .
JOURNAL OF POWER SOURCES, 2000, 86 (1-2) :383-389
[9]   CERAMIC FUEL-CELLS [J].
MINH, NQ .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1993, 76 (03) :563-588
[10]   Preparation of nickel coated YSZ powder for application as an anode for solid oxide fuel cells [J].
Pratihar, SK ;
Das Sharma, A ;
Basu, RN ;
Maiti, HS .
JOURNAL OF POWER SOURCES, 2004, 129 (02) :138-142