Synthesis of a Triptycene-Derived Bisparaphenylene-34-crown-10 and Its Complexation with Both Paraquat and Cyclobis(paraquat-p-phenylene)

被引：29

作者：

Jiang, Yi ^{[1
,2
]}

Cao, Jing ^{[1
,2
]}

Zhao, Jian-Min ^{[1
,2
]}

Xiang, Jun-Feng ^{[1
]}

Chen, Chuan-Feng ^{[1
]}

机构：

[1] Chinese Acad Sci, Beijing Natl Lab Mol Sci, Key Lab Mol Recognit & Funct, Inst Chem, Beijing 100190, Peoples R China

[2] Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2010年 / 75卷 / 05期

基金：

中国国家自然科学基金;

关键词：

MOLECULAR MECCANO; DONOR-ACCEPTOR; DERIVATIVES; HOST; TWEEZER; SALTS; CORE;

D O I：

10.1021/jo902571n

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel triptycene-derived bisparaphenylene-34-crown- 10(1) has been synthesized, and shown to form 1:1 stable complexes with both the paraquat G1.2PF(6) and the cyclobis(paraquat-p-phenylene) G2.4PF(6) in different complexation modes in solution and solid state. Moreover, it was found that both the coniplexes 1.G1.2PF(6) and 1.G2.4PF(6) were formed by charge transfer interactions, and did not dissociate upon the first one-electron reduction process of the bipyridinium ring.

引用

页码：1767 / 1770

页数：4

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