Synthesis and characterization of an open framework gallium selenide:: Ga4Se7(en)2•(enH)2

被引：24

作者：

Dong, YJ ^{[1
]}

Peng, Q ^{[1
]}

Wang, RJ ^{[1
]}

Li, YD ^{[1
]}

机构：

[1] Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China

来源：

INORGANIC CHEMISTRY | 2003年 / 42卷 / 06期

关键词：

D O I：

10.1021/ic0262536

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An open framework gallium selenide, Ga4Se7(en)(2).(enH)(2), has been prepared by the direct reaction of gallium (Ga) and selenium (Se) in ethylenediamine (en), in which both-covalent and hydrogen bonds have been employed to combine the inorganic structures and organic spacers to build layers with micropores. Its structure has been determined by X-ray diffraction. Its thermal and optical properties have been characterized by TGA and UV-vis, Raman, and IR spectroscopies, respectively.

引用

页码：1794 / 1796

页数：3

共 37 条

[1]

BEDARD RL, 1989, STUD SURF SCI CATAL, V49, P375

[2]

*BRUK AXS INC, 1999, PROGR SADABS

[3] A novel 3-dimensional open framework sulfide based upon the [In10S20]10- supertetrahedron:: DMA-InS-SB1 [J].

Cahill, CL ;

Ko, YH ;

Parise, JB .

CHEMISTRY OF MATERIALS, 1998, 10 (01) :19-21

[4]

Cheetham A. K., 1999, ANGEW CHEM, V111, P3466

[5]

Cheetham AK, 1999, ANGEW CHEM INT EDIT, V38, P3268, DOI 10.1002/(SICI)1521-3773(19991115)38:22<3268::AID-ANIE3268>3.0.CO

[6]

2-U

[7]

Choudhury A, 2002, ANGEW CHEM INT EDIT, V41, P158, DOI 10.1002/1521-3773(20020104)41:1<158::AID-ANIE158>3.0.CO

[8]

2-#

[9] Theoretical study of the structural and electronic properties of GaSe nanotubes [J].

Cote, M ;

Cohen, ML ;

Chadi, DJ .

PHYSICAL REVIEW B, 1998, 58 (08) :R4277-R4280

[10] Ordered porous materials for emerging applications [J].

Davis, ME .

NATURE, 2002, 417 (6891) :813-821

← 1 2 3 4 →