Comparison of energy-distribution functions calculated for gas-solid and liquid-solid adsorption data

被引：19

作者：

Dabrowski, A

Podkoscielny, P

Bülow, M

机构：

[1] Marie Curie Sklodowska Univ, Fac Chem, Dept Theoret Chem, PL-20031 Lublin, Poland

[2] BOC Proc Plants Technol, Murray Hill, NJ 07974 USA

来源：

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS | 2003年 / 212卷 / 2-3期

关键词：

energy distribution function; heterogeneity; regularisation method; excess isotherm; monolayer capacity;

D O I：

10.1016/S0927-7757(02)00331-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Comparison of the energy distribution functions obtained by employing the improved regularisation method with those related to the exponential equation for the identical systems is presented. The analysed gas-solid adsorption data comprises two sets of adsorption systems: benzene on silica gel at 303 K, and cyclohexane on silica gel at 303 K. In terms of the liquid-solid data, the system: benzene (1)+cyclohexane (2) on silica gel, was analysed at 303 K. Application of the regularisation method allows for more realistic description of the heterogeneity effects for the adsorption systems studied. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：109 / 114

页数：6

共 17 条

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