Versatile helical polymer films: Chiroptical inversion switching and memory with re-writable (RW) and write-once read-many (WORM) modes

被引:72
作者
Ohira, A
Okoshi, K
Fujiki, M
Kunitake, M
Naito, M
Hagihara, T
机构
[1] Nara Inst Sci & Technol, Grad Sch Mat Sci, Ikoma, Nara 6300101, Japan
[2] Kumamoto Univ, Dept Appl Chem & Biochem, Kumamoto 8608555, Japan
关键词
D O I
10.1002/adma.200400470
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Solid-state films of chiral polysilanes undergo an optical inversion (see Figure) above a helix-helix transition temperature, determined by the polymer molecular weight and by the thermal processing. These films could be used for re-writable or write-once, read-many data storage, depending on the molecular weight and the transition temperature.
引用
收藏
页码:1645 / +
页数:7
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