Low temperature preparation of nanocrystalline Mn2O3 via ethanol-thermal reduction of MnO2

被引：57

作者：

He, WL ^{[1
]}

Zhang, YC ^{[1
]}

Zhang, XX ^{[1
]}

Wang, H ^{[1
]}

Yan, H ^{[1
]}

机构：

[1] Beijing Polytech Univ, Key Lab Adv Funct Mat, China Educ Minist, Beijing 100022, Peoples R China

来源：

JOURNAL OF CRYSTAL GROWTH | 2003年 / 252卷 / 1-3期

关键词：

hydrothermal crystal growth; nanomaterials;

D O I：

10.1016/S0022-0248(03)00937-0

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

A solvothermal route has been developed to synthesize nanocrystalline Mn2O3 via the reduction of MnO2 using ethanol as the reducing agent as well as the solvent at 130degreesC. X-ray diffraction and X-ray photoelectron spectroscopy analysis revealed that the as-synthesized products are of tetragonal structure Mn2O3 (gamma-Mn2O3). Transmission electron spectroscopy image showed that the obtained gamma-Mn2O3 comprises square-shaped nanocrystallites with the sizes of about 50 nm. The formation mechanism of Mn2O3 was studied. (C) 2003 Elsevier Science B.V. All rights reserved.

引用

页码：285 / 288

页数：4

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