Structure and synthesis of anhydrobisfarnesol from Euphorbia lateriflora and asymmetric synthesis of (R)-sesquilavandulol

被引：14

作者：

Faure, S

Connolly, JD ^{[1
]}

Fakunle, CO

Piva, O

机构：

[1] Univ Glasgow, Dept Chem, Glasgow G12 8QQ, Lanark, Scotland

[2] Univ Reims, UMR 6519 CNRS, Lab Photochim, UFR Sci, F-51689 Reims, France

[3] Obafemi Awolowo Univ, Dept Chem, Ife, Nigeria

[4] Univ Lyon 1, UMR 5622 CNRS, Lab Chim Organ Photochim & Synth, F-69622 Villeurbanne, France

来源：

TETRAHEDRON | 2000年 / 56卷 / 49期

关键词：

terpenes; anhydrobisfarnesol; sesquilavandulol; photoisomerisation;

D O I：

10.1016/S0040-4020(00)00913-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Anhydrobisfarnesol has been isolated from the latex of Euphorbia lateriflora and assigned structure 4 on the basis of its spectroscopic properties. Its structure has been confirmed by synthesis using a photochemical isomerisation procedure. A similar approach has been used for the total synthesis of (R)-sesquilavandulol. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：9647 / 9653

页数：7

共 21 条

[1] Unusual reactions of methylsulfonyl esters: Syntheses of 3 alpha-methyl and 3 beta-methyl gibberellin A(20) [J].