A laser flash photolysis study of p-tolyl(trifluoromethyl)carbene

被引：48

作者：

Admasu, A

Gudmundsdottir, AD

Platz, MS

Watt, DS

Kwiatkowski, S

Crocker, PJ

机构：

[1] Ohio State Univ, Dept Chem, Columbus, OH 43210 USA

[2] Univ Kentucky, Dept Chem, Lexington, KY 40506 USA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1998年 / 05期

关键词：

D O I：

10.1039/a707586c

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

3-p-Tolyl-3-trifluoromethyldiazirine was studied by laser hash photolysis (LFP) to obtain the absolute kinetics of p-tolyl(trifluoromethyl)carbene 1. The absolute rate constants for the reactions of 1 with pyridine, ketones and quenchers of biological interest were obtained. The implications of the data for photoaffinity labeling experiments are discussed.

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页码：1093 / 1099

页数：7

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