Rational synthesis of a microporous metal-organic framework with PtS topology using a semi-rigid tetrahedral linker

被引：41

作者：

Liang, Li-Li ^{[1
]}

Zhang, Jun ^{[1
]}

Ren, Shi-Bin ^{[1
]}

Ge, Gen-Wu ^{[1
]}

Li, Yi-Zhi ^{[1
]}

Du, Hong-Bin ^{[1
]}

You, Xiao-Zeng ^{[1
]}

机构：

[1] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing Natl Lab Microstruct, Sch Chem & Chem Engn, Nanjing 210093, Peoples R China

来源：

CRYSTENGCOMM | 2010年 / 12卷 / 07期

基金：

中国国家自然科学基金;

关键词：

HYDROGEN STORAGE; MOLECULAR-SIEVE; SINGLE-CRYSTAL; SITES; SEPARATION; TRANSFORMATION; SORPTION; NETWORK; IONS;

D O I：

10.1039/b925903a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The assembly of a semi-rigid tetrahedral linker tetrakis[4-(carboxyphenyl)oxamethyl]methane acid (H(4)X) with Cu(II) yields a binodal 4,4-connected coordination framework of distorted PtS topology, which exhibits permanent porosity confirmed by gas adsorption experiments of N(2), H(2), CO(2), and CH(4).

引用

页码：2008 / 2010

页数：3

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