Nitroxide-mediated controlled free-radical emulsion polymerization of styrene and n-butyl acrylate with a water-soluble alkoxyamine as initiator

被引：111

作者：

Nicolas, J

Charleux, B

Guerret, O

Magnet, SP

机构：

[1] Univ Paris 06, Assoc CNRS, UMR 7610, Chim Lab Polymeres, F-75252 Paris 05, France

[2] ATOFINA, Groupement Rech Lacq, F-64170 Lacq, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 45期

关键词：

alkoxyamines; emulsions; living polymerization; nitroxides; polymerization;

D O I：

10.1002/anie.200460704

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Latex: Nitroxide-mediated emulsion polymerizations of n-butyl acrylate and styrene were successfully carried out in a multistep process, with a novel water-soluble SG1-based alkoxyamine as initiator. Fast reactions lead to stable latex particles containing polymers with controlled molar masses.

引用

页码：6186 / 6189

页数：4

共 19 条

[1]

[Anonymous], 2000, CONTROLLEDLIVING RAD

[2]

BATES RG, 1964, DETERMINATION PH, pCH7

[3] Nitroxide-mediated radical polymerization of styrene in emulsion [J].