CTAB-Mn3O4 nanocomposites: Synthesis, NMR and low temperature EPR studies

被引：31

作者：

Kavas, H. ^{[2
]}

Durmus, Z. ^{[1
]}

Senel, M. ^{[1
]}

Kazan, S. ^{[3
]}

Baykal, A. ^{[1
]}

Toprak, M. S. ^{[4
]}

机构：

[1] Fatih Univ, Dept Chem, TR-34500 Istanbul, Turkey

[2] Fatih Univ, Dept Phys, TR-34500 Istanbul, Turkey

[3] Gebze Inst Technol, Dept Phys, Fac Sci, TR-41400 Gebze, Turkey

[4] Royal Inst Technol, Funct Mat Div, SE-16440 Stockholm, Sweden

来源：

POLYHEDRON | 2010年 / 29卷 / 05期

关键词：

Nanostructures; Sonochemical synthesis; Nanocomposite; Mn3O4; NMR; EPR; MN3O4; NANOCRYSTALLITES; MAGNETIC-PROPERTIES; NANOPARTICLES; HAUSMANNITE; MONOLAYERS; NANORODS;

D O I：

10.1016/j.poly.2009.12.034

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We are reporting on the synthesis of Mn3O4 nanoparticles and CTAB-Mn3O4 nanocomposites via a sonochemical route using MnCl2, ethanol, NaOH and CTAB. The crystalline phase was identified as Mn3O4. The crystallite size of the CTAB-Mn3O4 nanocomposite was identified as 13 +/- 5 nm from X-ray line profile fitting and the particle size from TEM was 107.5 +/- 1.4 nm. The interaction between CEAB and the Mn3O4 nanoparticles was investigated by FTIR and H-1 NMR spectroscopies. Two different magnetic phase transitions were observed for both samples below the Curie temperature (43 degrees C) by using a low temperature Electron Paramagnetic Resonance (EPR) technique. Also we determined the effect of the capping with CTAB on the reduction in absorbed power. (C) 2010 Elsevier Ltd. All rights reserved.

引用

页码：1375 / 1380

页数：6

共 32 条

[1] Synthesis of nanocrystalline Mn3O4 at 100 °C [J].