Bimetallic cluster complexes: synthesis, structures and applications to catalysis

被引:72
作者
Adams, RD [1 ]
Captain, B
机构
[1] Univ S Carolina, Dept Chem & Biochem, Columbia, SC 29208 USA
[2] Univ S Carolina, NanoCtr, Columbia, SC 29208 USA
关键词
bimetallic; platinum; ruthenium; catalysis; alkynes;
D O I
10.1016/j.jorganchem.2004.08.001
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A brief history of the seminal discoveries in the field of bimetallic cluster complexes with discussion of their structures is presented. A review of some recent studies of palladium and platinum-ruthenium cluster complexes is included with a discussion of applications of these complexes in the area of homogeneous hydrogenation catalysis of alkynes. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:4521 / 4529
页数:9
相关论文
共 81 条
[1]   SOME PI-CYCLOPENTADIENYL-MOLYBDENUM AND PI-CYCLOPENTADIENYL-TUNGSTEN CARBONYLS [J].
ABEL, EW ;
SINGH, A ;
WILKINSON, G .
JOURNAL OF THE CHEMICAL SOCIETY, 1960, (MAR) :1321-1324
[2]  
Adams R. D., 1990, CHEM METAL CLUSTER C, P121
[3]   Platinum participation in the hydrogenation of phenylacetylene by Ru5(CO)15(C)[Pt(PBu3t)] [J].
Adams, RD ;
Captain, B ;
Zhu, L .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (10) :3042-3043
[4]   Remarkable dynamical opening and closing of platinum and palladium pentaruthenium carbido carbonyl cluster complexes [J].
Adams, RD ;
Captain, B ;
Fu, W ;
Pellechia, PJ ;
Smith, MD .
INORGANIC CHEMISTRY, 2003, 42 (06) :2094-2101
[5]   Does a metal to metal "ligand" effect influence the catalytic activity of bimetallic cluster complexes?: Synthesis and catalytic activity of Pt3Ru6(CO)19(SMe2)(μ3-PhC2Ph)(μ3-H)(μ-H) [J].
Adams, RD ;
Barnard, TS .
ORGANOMETALLICS, 1998, 17 (13) :2885-2890
[6]   Lewis acid-base interactions between metal atoms and their applications for the synthesis of bimetallic cluster complexes [J].
Adams, RD ;
Captain, B ;
Fu, W ;
Smith, MD .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (20) :5628-5629
[7]   New mixed metal cluster complexes containing platinum.: The synthesis and structural characterizations of PtFe4(CO)12(COD)(μ5-C) and PtFe4(CO)12(PMe2Ph)2(μ5-C) [J].
Adams, RD ;
Captain, B ;
Fu, W .
JOURNAL OF CLUSTER SCIENCE, 2001, 12 (01) :303-312
[8]   LIGAND INFLUENCES ON THE STATE OF CLUSTER AGGREGATION - LIGAND-DEPENDENT FORMATION OF CLUSTER COMPLEXES WITH [PTRU2]1, [PTRU2]2, [PTRU2]3 METAL GROUPINGS [J].
ADAMS, RD ;
CHEN, G ;
WANG, JG ;
WU, WG .
ORGANOMETALLICS, 1990, 9 (04) :1339-1341
[9]   Catalytic hydrosilylation of diarylalkynes by layer-segregated platinum-ruthenium cluster complexes Pt3Ru6(CO)20(μ3-RC2R)(μ3-H)(μ-H) [J].
Adams, RD ;
Barnard, TS .
ORGANOMETALLICS, 1998, 17 (12) :2567-2573
[10]   CATALYTIC-HYDROGENATION OF DIPHENYLACETYLENE BY A LAYER-SEGREGATED PLATINUM-RUTHENIUM CLUSTER COMPLEX [J].
ADAMS, RD ;
BARNARD, TS ;
LI, ZY ;
WU, WG ;
YAMAMOTO, JH .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (20) :9103-9113