A new approach to infrared spectroelectrochemistry using a fiber-optic probe: Application to organometallic redox chemistry

被引：40

作者：

Shaw, MJ ^{[1
]}

Geiger, WE ^{[1
]}

机构：

[1] UNIV VERMONT,DEPT CHEM,BURLINGTON,VT 05405

来源：

ORGANOMETALLICS | 1996年 / 15卷 / 01期

关键词：

D O I：

10.1021/om9507179

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A mid-IR fiber-optic cable operating as a ''dip'' probe has been used to obtain IR spectra of electrolysis solutions. The probe is employed in conventional electrochemical cells to sample the bulk of solution before, during, and after electrolysis. Unlike other spectroelectrochemical methods, this technique requires no cell design compromises which diminish the accuracy of the electrochemical data.

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页码：13 / 15

页数：3

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