Formation of ZMM-n:: The composite materials having both natures of zeolites and mesoporous silica materials

被引:25
作者
Ogura, Masaru
Zhang, Yiwen
Elangovan, S. P.
Okubo, Tatsuya
机构
[1] Univ Tokyo, Inst Ind Sci, Dept Mat & Environm Sci, Meguro Ku, Tokyo 1538505, Japan
[2] Univ Tokyo, Dept Chem Syst Engn, Tokyo, Japan
关键词
zeolite; mesoporous silica; composite; carbon filling; alummosilicate; vapor-phase transport;
D O I
10.1016/j.micromeso.2006.10.032
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The formation mechanism of ZMM-n, composite mesoporous aluminosilicate materials, which are obtained by use of vapor phase transport of structure-directing agent for zeolites, is clarified. Filling the mesopores by carbon is essential to preserve the mesoporous structure of the source, and addition of aluminum on mesoporous silica critically determines the formation rate and stability of zeolitic building units on the surface of mesopores. (c) 2006 Elsevier Inc. All rights reserved.
引用
收藏
页码:224 / 230
页数:7
相关论文
共 26 条
[1]   Synthesis of ZSM-5 films and monoliths with bimodal micro/mesoscopic structures [J].
Cho, SI ;
Choi, SD ;
Kim, JH ;
Kim, GJ .
ADVANCED FUNCTIONAL MATERIALS, 2004, 14 (01) :49-54
[2]   A MOLECULAR-SIEVE WITH 18-MEMBERED RINGS [J].
DAVIS, ME ;
SALDARRIAGA, C ;
MONTES, C ;
GARCES, J ;
CROWDER, C .
NATURE, 1988, 331 (6158) :698-699
[4]   Investigation of synthesizing MCM-41/ZSM-5 composites [J].
Huang, LM ;
Guo, WP ;
Deng, P ;
Xue, ZY ;
Li, QZ .
JOURNAL OF PHYSICAL CHEMISTRY B, 2000, 104 (13) :2817-2823
[5]   PROPERTIES OF THE END MEMBERS IN THE PENTASIL-FAMILY OF ZEOLITES - CHARACTERIZATION AS ADSORBENTS [J].
JACOBS, PA ;
BEYER, HK ;
VALYON, J .
ZEOLITES, 1981, 1 (03) :161-168
[6]   Mesoporous zeolite single crystals [J].
Jacobsen, CJH ;
Madsen, C ;
Houzvicka, J ;
Schmidt, I ;
Carlsson, A .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (29) :7116-7117
[7]   Synthesis of new, nanoporous carbon with hexagonally ordered mesostructure [J].
Jun, S ;
Joo, SH ;
Ryoo, R ;
Kruk, M ;
Jaroniec, M ;
Liu, Z ;
Ohsuna, T ;
Terasaki, O .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (43) :10712-10713
[8]   Composites of micro- and mesoporous materials:: simultaneous syntheses of MFI/MCM-41 like phases by a mixed template approach [J].
Karlsson, A ;
Stöcker, M ;
Schmidt, R .
MICROPOROUS AND MESOPOROUS MATERIALS, 1999, 27 (2-3) :181-192
[9]  
Kloetstra KR, 1997, CHEM COMMUN, P2281
[10]   Steam-stable aluminosilicate mesostructures assembled from zeolite type Y seeds [J].
Liu, Y ;
Zhang, WZ ;
Pinnavaia, TJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (36) :8791-8792