The formation of gigantic hollow silica spheres from an EO76-PO29EO76/butanol/ethanol/H2O quaternary system

被引：40

作者：

Sun, Q

Magusin, PCMM

Mezari, B

Panine, P

van Santen, RA

Sommerdijk, NAJM

机构：

[1] Eindhoven Univ Technol, Lab Macromol & Organ Chem, NL-5600 MB Eindhoven, Netherlands

[2] Eindhoven Univ Technol, Schuit Inst Catalysis, NL-5600 MB Eindhoven, Netherlands

[3] European Synchrotron Radiat Facil, F-38043 Grenoble 9, France

来源：

JOURNAL OF MATERIALS CHEMISTRY | 2005年 / 15卷 / 02期

关键词：

D O I：

10.1039/b413363c

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Gigantic hollow silica spheres with a hierarchical intra- and inter-particle porosity were obtained from an EO(76)-PO(29)-EO(76)/butanol/ethanol/H(2)O quaternary system, which is unique in its extremely rapid silica condensation and in the resulting hierarchical morphology.

引用

收藏

页码：256 / 259

页数：4

相关论文

共 25 条

[1] Nanoengineering of inorganic and hybrid hollow spheres by colloidal templating [J].

Caruso, F ;

Caruso, RA ;

Möhwald, H .

SCIENCE, 1998, 282 (5391) :1111-1114

[2] Controlled formation of silica particles from tetraethyl orthosilicate in nonionic water-in-oil microemulsions [J].

Chang, CL ;

Fogler, HS .

LANGMUIR, 1997, 13 (13) :3295-3307

[3] A PHASE OF LIPOSOMES WITH ENTANGLED TUBULAR VESICLES [J].

CHIRUVOLU, S ;

WARRINER, HE ;

NARANJO, E ;

IDZIAK, SHJ ;

RADLER, JO ;

PLANO, RJ ;

ZASADZINSKI, JA ;

SAFINYA, CR .

SCIENCE, 1994, 266 (5188) :1222-1225

[4] Formation of a new Ia(3)over-bard cubic meso-structured silica via triblock copolymer-assisted synthesis [J].

Flodström, K ;

Alfredsson, V ;

Källrot, N .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (15) :4402-4403

[5] Interfacial synthesis of hollow microspheres of mesostructured silica [J].

Fowler, CE ;

Khushalani, D ;

Mann, S .

CHEMICAL COMMUNICATIONS, 2001, (19) :2028-2029

[6]

GREG SJ, 1995, ADSORPTION SURFACE A

[7] Simple preparation of monodisperse hollow silica particles without using templates [J].

Hah, HJ ;

Kim, JS ;

Jeon, BJ ;

Koo, SM ;

Lee, YE .

CHEMICAL COMMUNICATIONS, 2003, (14) :1712-1713

[8]

Hubert DHW, 2000, ADV MATER, V12, P1286, DOI 10.1002/1521-4095(200009)12:17<1286::AID-ADMA1286>3.0.CO

[9]

2-7

[10] ORDERED MESOPOROUS MOLECULAR-SIEVES SYNTHESIZED BY A LIQUID-CRYSTAL TEMPLATE MECHANISM [J].

KRESGE, CT ;

LEONOWICZ, ME ;

ROTH, WJ ;

VARTULI, JC ;

BECK, JS .

NATURE, 1992, 359 (6397) :710-712