Hybrid molecular conductors

被引:125
作者
Coronado, E [1 ]
Galán-Mascarós, JR [1 ]
机构
[1] Univ Valencia, Inst Ciencia Mol, E-46100 Burjassot, Spain
关键词
D O I
10.1039/b415940n
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
One of the most important trends in the field of organic conductors aims towards the design of hybrid materials, following the strategy of combining in a single compound organic cationic radicals able to give rise to conducting architectures with functional molecular anions able to add a second physical property of interest. Ferromagnetic metals, magnetic superconductors, chiral conductors and switchable conductors are some of the most recent and spectacular materials obtained from this approach. The design and physical studies of some relevant examples are discussed and highlighted.
引用
收藏
页码:66 / 74
页数:9
相关论文
共 58 条
[1]   Helical polyacetylene synthesized with a chiral nematic reaction field [J].
Akagi, K ;
Piao, G ;
Kaneko, S ;
Sakamaki, K ;
Shirakawa, H ;
Kyotani, M .
SCIENCE, 1998, 282 (5394) :1683-1686
[2]   Proton transfer and a dielectric phase transition in the molecular conductor (HDABCO+)2(TCNQ)3 [J].
Akutagawa, T ;
Takeda, S ;
Hasegawa, T ;
Nakamura, T .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (01) :291-294
[3]  
Akutagawa T, 2002, CHEM-EUR J, V8, P4402, DOI 10.1002/1521-3765(20021004)8:19<4402::AID-CHEM4402>3.0.CO
[4]  
2-H
[5]   Effect of included guest molecules on the normal state conductivity and superconductivity of β"-(ET)4[(H3O)Ga(C2O4)3]•G (G = pyridine, nitrobenzene) [J].
Akutsu, H ;
Akutsu-Sato, A ;
Turner, SS ;
Le Pevelen, D ;
Day, P ;
Laukhin, V ;
Klehe, AK ;
Singleton, J ;
Tocher, DA ;
Probert, MR ;
Howard, JAK .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (42) :12430-12431
[6]   Structures and physical properties of BEDT-TTF salts containing channels of protons [J].
Akutsu-Sato, A ;
Akutsu, H ;
Turner, SS ;
Le Pevelen, D ;
Day, P ;
Light, ME ;
Hursthouse, MB ;
Akutagawa, T ;
Nakamura, T .
SYNTHETIC METALS, 2003, 135 (1-3) :597-598
[7]   A molecular metal ferromagnet from the organic donor bis(ethylenedithio)tetraselenafulvalene and bimetallic oxalate complexes [J].
Alberola, A ;
Coronado, E ;
Galán-Mascarós, JR ;
Giménez-Saiz, C ;
Gómez-García, CJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (36) :10774-10775
[8]   Multifunctionality in hybrid molecular materials:: Design of ferromagnetic molecular metals [J].
Alberola, A ;
Coronado, E ;
Galán-Mascarós, JR ;
Giménez-Saiz, C ;
Gómez-García, CJ ;
Martinez-Ferrero, E ;
Murcia-Martínez, A .
SYNTHETIC METALS, 2003, 135 (1-3) :687-689
[9]  
[Anonymous], 1997, HDB ORGANIC CONDUCTI
[10]   Diffraction studies of photoexcited crystals: Metastable nitrosyl-linkage isomers of sodium nitroprusside [J].
Carducci, MD ;
Pressprich, MR ;
Coppens, P .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (11) :2669-2678