Interpretation of biomass gasification yields regarding temperature intervals under nitrogen-steam atmosphere

被引：37

作者：

Haykiri-Acma, H. ^{[1
]}

Yaman, S. ^{[1
]}

机构：

[1] Istanbul Tech Univ, Met Engn Fac, Dept Chem Engn, TR-34469 Istanbul, Turkey

来源：

FUEL PROCESSING TECHNOLOGY | 2007年 / 88卷 / 04期

关键词：

biomass; gasification; steam; nitrogen; thermogravimetry;

D O I：

10.1016/j.fuproc.2006.11.002

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Gasification of some agricultural waste biomass samples (sunflower shell, pine cone, cotton refuse, and olive refuse) and colza seed was performed using a thermogravimetric analyzer at temperatures up to 1273 K with a constant heating rate of 20 K/min under a dynamic nitrogen-steam atmosphere. Derivative thermogravimetric analysis profiles of the samples were derived from the non-isothermal thermogravimetric analysis data. Gasification yields of the biomass samples at temperature intervals of 473-553 K, 553-653 K, 653-773 K, 773-973 K, and 973-1173 K were investigated considering the successive stages of "evolution of carbon oxides", "start of hydrocarbon evolution", "evolution of hydrocarbons", "dissociation", and "evolution of hydrogen", respectively. Although, there were some interactions between these stages, some evident relations were observed between the gasification yields in a given stage and the chemical properties of the parent biomass materials. (C) 2006 Elsevier B.V. All rights reserved.

引用

页码：417 / 425

页数：9

共 40 条

[1]

*ASTM, 2001, D1105 ASTM

[2] THE TECHNICAL AND ECONOMIC-FEASIBILITY OF BIOMASS GASIFICATION FOR POWER-GENERATION [J].

BRIDGWATER, AV .

FUEL, 1995, 74 (05) :631-653

[3] Hydrogen rich gas mixture from olive husk via pyrolysis [J].

Çaglar, A ;

Demirbas, A .

ENERGY CONVERSION AND MANAGEMENT, 2002, 43 (01) :109-117

[4] KINETIC PARAMETERS FROM THERMOGRAVIMETRIC DATA [J].

COATS, AW ;

REDFERN, JP .

NATURE, 1964, 201 (491) :68-&

[5] Hydrogen production from biomass gasification on nickel catalysts - Tests for dry reforming of methane [J].

Courson, C ;

Udron, L ;

Swierczynski, D ;

Petit, C ;

Kiennemann, A .

CATALYSIS TODAY, 2002, 76 (01) :75-86

[6] RELATIVE RATES OF CARBON GASIFICATION IN OXYGEN, STEAM AND CARBON-DIOXIDE [J].

DEGROOT, WF ;

RICHARDS, GN .

CARBON, 1989, 27 (02) :247-252

[7] Pyrolysis and steam gasification processes of black liquor [J].

Demirbas, A .

ENERGY CONVERSION AND MANAGEMENT, 2002, 43 (07) :877-884

[8] Steam gasification of Cynara cardunculus L.:: influence of variables [J].

Encinar, JM ;

González, JF ;

González, J .

FUEL PROCESSING TECHNOLOGY, 2002, 75 (01) :27-43

[9] Catalysed and uncatalysed steam gasification of eucalyptus char:: influence of variables and kinetic study [J].

Encinar, JM ;

González, JF ;

Rodríguez, JJ ;

Ramiro, MJ .

FUEL, 2001, 80 (14) :2025-2036

[10] The study of reactions influencing the biomass steam gasification process [J].

Franco, C ;

Pinto, F ;

Gulyurtlu, I ;

Cabrita, I .

FUEL, 2003, 82 (07) :835-842

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