A reversible octahedral to trigonal-bipyramidal cobalt coordination change in an aquo-accessible coordination network

被引：20

作者：

Fu, Shu-Juan ^{[1
]}

Cheng, Ching-Yuan ^{[1
]}

Lin, Kuan-Jiuh ^{[1
]}

机构：

[1] Natl Chung Hsing Univ, Dept Chem, Ctr Nanosci & Nanotechnol, Taichung 402, Taiwan

来源：

CRYSTAL GROWTH & DESIGN | 2007年 / 7卷 / 08期

关键词：

D O I：

10.1021/cg070361r

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An aquo-accessible chromatic change in a crystal was induced by means of a reversible coordination geometry shift from octahedra in [Co(C12H8N2)(HO3P-C2H4-PO3H)(OH2)(2)] (1) to trigonal-bipyramid in [Co(C12H8N2)(HO3P-C2H4-PO3H)] (2) at the cobalt(II) center; the crystal-to-crystal phase transition was confirmed by powder X-ray diffraction and solid-state UV-vis diffuse reflectance spectra.

引用

页码：1381 / 1384

页数：4

共 31 条

[1] Zinc saccharate: A robust, 3D coordination network with two types of isolated, parallel channels, one hydrophilic and the other hydrophobic [J].

Abrahams, BF ;

Moylan, M ;

Orchard, SD ;

Robson, R .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (16) :1848-1851

[2]

Biradha K, 2002, ANGEW CHEM INT EDIT, V41, P3392, DOI 10.1002/1521-3773(20020916)41:18<3392::AID-ANIE3392>3.0.CO

[3]

2-V

[4] Permanent microporosity and enantioselective sorption in a chiral open framework [J].

Bradshaw, D ;

Prior, TJ ;

Cussen, EJ ;

Claridge, JB ;

Rosseinsky, MJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (19) :6106-6114

[5] A chemically functionalizable nanoporous material [Cu3(TMA)2(H2O)3]n [J].

Chui, SSY ;

Lo, SMF ;

Charmant, JPH ;

Orpen, AG ;

Williams, ID .

SCIENCE, 1999, 283 (5405) :1148-1150

[6] Ordered porous materials for emerging applications [J].

Davis, ME .

NATURE, 2002, 417 (6891) :813-821

[7] PREPARATION, CLATHRATION ABILITY, AND CATALYSIS OF A 2-DIMENSIONAL SQUARE NETWORK MATERIAL COMPOSED OF CADMIUM(II) AND 4,4'-BIPYRIDINE [J].

FUJITA, M ;

KWON, YJ ;

WASHIZU, S ;

OGURA, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (03) :1151-1152

[8] Reversible repositioning of zinc atoms within single crystals of a zinc polycarboxylate with an open-framework structure [J].

Hanson, K ;

Calin, N ;

Bugaris, D ;

Scancella, M ;

Sevov, SC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (34) :10502-10503

[9] Synthesis and characterization of a series of edge-sharing octahedral-tetrahedral-octahedral linear trinuclear complexes [M3(L1O)4]2+, where M = Mn2+, Co2+, Ni2+, Cu2+, and Zn2+ and L1OH is the "heteroscorpionate" ligand (2-hydroxyphenyl)bis(pyrazolyl)methane [J].

Higgs, TC ;

Spartalian, K ;

O'Connor, CJ ;

Matzanke, BF ;

Carrano, CJ .

INORGANIC CHEMISTRY, 1998, 37 (09) :2263-2272

[10] Model complexes of cobalt-substituted matrix metalloproteinases: Tools for inhibitor design [J].

Jacobsen, Faith E. ;

Breece, Robert M. ;

Myers, William K. ;

Tierney, David L. ;

Cohen, Seth M. .

INORGANIC CHEMISTRY, 2006, 45 (18) :7306-7315

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