Single-wall carbon nanotubes as immobilization material for glucose biosensor

被引:29
作者
Xue, HG [1 ]
Sun, WL [1 ]
He, BJ [1 ]
Shen, ZQ [1 ]
机构
[1] Zhejiang Univ, Inst Polymer Sci, Hangzhou 310027, Peoples R China
关键词
enzyme immobilization; carbon nanotubes; glucose oxidase; biosensor;
D O I
10.1016/S0379-6779(02)00919-0
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
An application of carbon nanotubes as immobilization materials for biosensor was described for the first time. Single-wall carbon nanotubes (SWNTs) functionalized with carboxylic acid groups were cast on platinum electrode. The film of SWNTs was used to immobilize glucose oxidase by covalent combine method forming a glucose biosensor. The biosensor showed stable amperometric response at a low applied potential (0.40 V), a wide response range of pH (5.5-8) and good stability (kept 90% activity after 4 months).
引用
收藏
页码:831 / 832
页数:2
相关论文
共 13 条
[1]   Solution properties of single-walled carbon nanotubes [J].
Chen, J ;
Hamon, MA ;
Hu, H ;
Chen, YS ;
Rao, AM ;
Eklund, PC ;
Haddon, RC .
SCIENCE, 1998, 282 (5386) :95-98
[2]   Noncovalent sidewall functionalization of single-walled carbon nanotubes for protein immobilization [J].
Chen, RJ ;
Zhang, YG ;
Wang, DW ;
Dai, HJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (16) :3838-3839
[3]   Extreme oxygen sensitivity of electronic properties of carbon nanotubes [J].
Collins, PG ;
Bradley, K ;
Ishigami, M ;
Zettl, A .
SCIENCE, 2000, 287 (5459) :1801-1804
[4]   The immobilisation of proteins in carbon nanotubes [J].
Davis, JJ ;
Green, MLH ;
Hill, HAO ;
Leung, YC ;
Sadler, PJ ;
Sloan, J ;
Xavier, AV ;
Tsang, SC .
INORGANICA CHIMICA ACTA, 1998, 272 (1-2) :261-266
[5]   Direct growth of single-walled carbon nanotube scanning probe microscopy tips [J].
Hafner, JH ;
Cheung, CL ;
Lieber, CM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (41) :9750-9751
[6]   HELICAL MICROTUBULES OF GRAPHITIC CARBON [J].
IIJIMA, S .
NATURE, 1991, 354 (6348) :56-58
[7]   ROTATING-RING-DISK ENZYME ELECTRODE FOR BIOCATALYSIS KINETIC-STUDIES AND CHARACTERIZATION OF THE IMMOBILIZED ENZYME LAYER [J].
KAMIN, RA ;
WILSON, GS .
ANALYTICAL CHEMISTRY, 1980, 52 (08) :1198-1205
[8]   Investigation of the electrochemical and electrocatalytic behavior of single-wall carbon nanotube film on a glassy carbon electrode [J].
Luo, HX ;
Shi, ZJ ;
Li, NQ ;
Gu, ZN ;
Zhuang, QK .
ANALYTICAL CHEMISTRY, 2001, 73 (05) :915-920
[9]  
SWOBODA BEP, 1965, J BIOL CHEM, V240, P2209
[10]   Room-temperature transistor based on a single carbon nanotube [J].
Tans, SJ ;
Verschueren, ARM ;
Dekker, C .
NATURE, 1998, 393 (6680) :49-52