Conduction in the positive-ion depleted region of alkali borate glasses

被引：12

作者：

Doi, A ^{[1
]}

Watanabe, K ^{[1
]}

机构：

[1] Nagoya Inst Technol, Dept Mat, Nagoya, Aichi 466, Japan

来源：

SOLID STATE IONICS | 1997年 / 104卷 / 3-4期

关键词：

electrode effects; positive-ion depletion; borate glasses;

D O I：

10.1016/S0167-2738(97)00431-1

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A.c. measurements on several alkali borate glasses were made at high temperatures. It was suggested that the positive-ion depleted region (PDR) which develops near the temporary anode during each halfcycle is an electric double layer formed by uncompensated negatively charged species and their mirror image and that, as an applied voltage increases, conduction of the electrons and/or negatively charged ionic species in the PDR as well as field-assisted injection of the gold ions from the gold anode take place.

引用

页码：215 / 225

页数：11

共 20 条

[1] ELECTRODE POLARIZATION IN ALKALI-CONTAINING GLASSES [J].

CARLSON, DE ;

STOCKDALE, GF ;

HANG, KW .

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1972, 55 (07) :337-+

[2] DISCRIMINATION BETWEEN CONDUCTION AND POLARIZATION PROCESSES IN AN AC ELECTRIC-FIELD [J].

DO, A .

JOURNAL OF APPLIED PHYSICS, 1988, 63 (01) :121-125

[3]

DOI A, 1983, JPN J APPL PHYS 1, V22, P228, DOI 10.1143/JJAP.22.228

[4]

DOI A, 1990, J APPL PHYS, V67, P691, DOI 10.1063/1.345773

[5]

DOI A, 1992, SOLID STATE IONICS, V57, P15, DOI 10.1016/0167-2738(92)90057-V

[6]

DOI A, 1989, J MATER SCI, V24, P749, DOI 10.1007/BF01107469

[7]

DOI A, 1980, J MATER SCI, V15, P3047, DOI 10.1007/BF00550374

[8] Positive-ion depletion out of the anode region of glass [J].

Doi, A ;

Itoh, H .

SOLID STATE IONICS, 1995, 82 (3-4) :123-127

[9]

DOI A, 1985, J MATER SCI, V20, P1787, DOI 10.1007/BF00555285

[10]

DOI A, 1987, J MATER SCI, V22, P761, DOI 10.1007/BF01103509

← 1 2 →