A ferromagnetic mixed-valent Mn supertetrahedron: Towards low-temperature magnetic refrigeration with molecular clusters

被引：178

作者：

Manoli, Maria

Johnstone, Russell D. L.

Parsons, Simon

Murrie, Mark

Affronte, Marco

Evangelisti, Marco

Brechin, Euan K.

机构：

[1] CNR, INFM, Natl Res Ctr NanoStruct & BioSyst Surfaces S3, I-41100 Modena, Italy

[2] Univ Edinburgh, Sch Chem, Edinburgh EH9 3JJ, Midlothian, Scotland

[3] Univ Glasgow, Dept Chem, Glasgow G12 8QQ, Lanark, Scotland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 24期

基金：

英国工程与自然科学研究理事会;

关键词：

cluster compounds; ferromagnetism; magnetic properties; magnetocaloric effect; manganese;

D O I：

10.1002/anie.200701027

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Fridge magnet: A decametallic mixed-valent Mn supertetrahedron (see picture; M purple, O red, N blue, Br brown, C gray) displays dominant ferromagnetic exchange and a spin ground state of S = 22. The magnetic behavior of the cluster makes it suitable for use as a low-temperature magnetic refrigerant. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

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收藏

页码：4456 / 4460

页数：5

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