New approach for size- and shape-controlled preparation of pd nanoparticles with organic ligands. Synthesis and application in catalysis

被引：125

作者：

Ananikov, Valentine P.

Orlov, Nikolay V.

Beletskaya, Irina P.

Khrustalev, Victor N.

Antipin, Mikhail Yu.

Timofeeva, Tatiana V.

机构：

[1] Russian Acad Sci, Zelinsky Inst Organ Chem, Moscow 119917, Russia

[2] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119899, Russia

[3] Russian Acad Sci, Nesmeyanov Inst Organoelement Cpd, Moscow, Russia

[4] New mexico Highlands Univ, Dept Nat Sci, Las Vegas, NM 87701 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2007年 / 129卷 / 23期

关键词：

D O I：

10.1021/ja071727r

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel approach was developed to prepare Pd nanoparticles with organic ligands in high yields. The structural unit of the Pd species was constructed involving Pd-S bonds. The synthesized Pd particles were highly selective catalysts of S-H bond addition to alkynes under microwave heating. An X-ray diffraction study of one of the products of the addition reaction revealed unusual supramolecular organization of cation/anion layers.

引用

页码：7252 / +

页数：3

共 44 条

[1] Highly efficient nickel-based heterogeneous catalytic system with nanosized structural organization for selective Se-H bond addition to terminal and internal alkynes [J].