Probing the transition state with negative ion photodetachment: experiment and theory

被引：103

作者：

Neumark, DM ^{[1
]}

机构：

[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

[2] Univ Calif Berkeley, Lawrence Berkeley Lab, Div Chem Sci, Berkeley, CA 94720 USA

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2005年 / 7卷 / 03期

关键词：

D O I：

10.1039/b417886f

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Experimental and theoretical results are presented on the spectroscopy of transition states and pre-reactive van der Waals wells using negative ion photodetachment. Several benchmark reactions are discussed, including the F + H-2, OH + H-2, and F + OH reactions, as well as the isomerization of cyclo-octatetraene. Photoelectron spectra of clustered transtion state precursor anions are presented, which examine the effects of solvation on anion structure and transition state dynamics. Finally, new experiments on the photodetachment of ClH2- are discussed in which the Cl . H-2 van der Waals well is probed.

引用

页码：433 / 442

页数：10

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