Catalytic dehydrohalogenation of polychlorinated biphenyls - Part II: Studies on a continuous process

被引：53

作者：

Forni, P ^{[1
]}

Prati, L ^{[1
]}

Rossi, M ^{[1
]}

机构：

[1] Univ Milan, Dipartimento Chim Inorgan Met Organ & Analit, Ctr CNR, Progetto Strategico Tecnol Chim Innovat, I-20133 Milan, Italy

来源：

APPLIED CATALYSIS B-ENVIRONMENTAL | 1997年 / 14卷 / 1-2期

关键词：

catalysis; dehalogenation; palladium; PCB;

D O I：

10.1016/S0926-3373(97)00011-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A convenient method for the environmentally friendly disposal of polychlorinated biphenyls (PCB), based on catalytic dehalogenation under mild conditions, is reported. By using 0.5% Pd on carbon in a fixed bed reactor at H(2) atmospheric pressure and at 453-503 K it was possible to obtain high conversion of PCB to HCl and hydrocarbons, mainly biphenyl. (C) 1997 Elsevier Science B.V.

引用

页码：49 / 53

页数：5

共 13 条

[1] Catalytic reduction of polyhalogenated aromatic hydrocarbons by Cu(I) under Dow-Phenol conditions [J].