Assay system for the herbicide 2,4-dichlorophenoxyacetic acid using a molecularly imprinted polymer as an artificial recognition element

被引：233

作者：

Haupt, K ^{[1
]}

Dzgoev, A ^{[1
]}

Mosbach, K ^{[1
]}

机构：

[1] Univ Lund, Dept Pure & Appl Biochem, Ctr Chem, S-22100 Lund, Sweden

来源：

ANALYTICAL CHEMISTRY | 1998年 / 70卷 / 03期

关键词：

D O I：

10.1021/ac9711549

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Noncovalent molecular imprinting of a synthetic polymer with the herbicide 2,4-dichlorophenoxyacetic acid has been achieved in the presence of the polar solvents methanol and water. Formation of the prearranged complex relied on hydrophobic and ionic interactions between the template and the functional monomer 4-vinylpyridine. The polymer obtained binds the original template with an appreciable selectivity over structurally related compounds. The potential use of micrometer-sized imprinted polymer particles as the recognition element in a radioligand binding assay for 2,4-dichlorophenoxyacetic acid is demonstrated.

引用

页码：628 / 631

页数：4

共 19 条

[1] Application of molecular imprinting to the development of aqueous buffer and organic solvent based radioligand binding assays for (S)-propranolol
Andersson, LI
[J]. ANALYTICAL CHEMISTRY, 1996, 68 (01) : 111 - 117
[2] Microformat imaging ELISA for pesticide determination
Dzgoev, A
Mecklenburg, M
Larsson, PO
Danielsson, B
[J]. ANALYTICAL CHEMISTRY, 1996, 68 (19) : 3364 - 3369
[3] DIRECT ENANTIOSEPARATION OF BETA-ADRENERGIC BLOCKERS USING A CHIRAL STATIONARY PHASE PREPARED BY MOLECULAR IMPRINTING
FISCHER, L
MULLER, R
EKBERG, B
MOSBACH, K
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (24) : 9358 - 9360
[4] MONOCLONAL ELISA FOR 2,4-DICHLOROPHENOXYACETIC ACID - CHARACTERIZATION OF ANTIBODIES AND ASSAY OPTIMIZATION
FRANEK, M
KOLAR, V
GRANATOVA, M
NEVORANKOVA, Z
[J]. JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 1994, 42 (06) : 1369 - 1374
[5] IMMUNOASSAYS FOR THE DETECTION OF 2,4-D AND PICLORAM IN RIVER WATER AND URINE
HALL, JC
DESCHAMPS, RJA
KRIEG, KK
[J]. JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 1989, 37 (04) : 981 - 984
[6] MOLECULAR IMPRINTING APPROACH FOR THE RECOGNITION OF ADENINE IN AQUEOUS-MEDIUM AND HYDROLYSIS OF ADENOSINE 5'-TRIPHOSPHATE
MATHEW, J
BUCHARDT, O
[J]. BIOCONJUGATE CHEMISTRY, 1995, 6 (05) : 524 - 528
[7] Solid-phase extraction of a triazine herbicide using a molecularly imprinted synthetic receptor
Matsui, J
Okada, M
Tsuruoka, M
Takeuchi, T
[J]. ANALYTICAL COMMUNICATIONS, 1997, 34 (03): : 85 - 87
[8] MOLECULAR RECOGNITION IN CONTINUOUS POLYMER RODS PREPARED BY A MOLECULAR IMPRINTING TECHNIQUE
MATSUI, J
KATO, T
TAKEUCHI, T
SUZUKI, M
YOKOYAMA, K
TAMIYA, E
KARUBE, I
[J]. ANALYTICAL CHEMISTRY, 1993, 65 (17) : 2223 - 2224
[9] The emerging technique of molecular imprinting and its future impact on biotechnology
Mosbach, K
Ramstrom, O
[J]. BIO-TECHNOLOGY, 1996, 14 (02): : 163 - 170
[10] POLYMER SYNTHESIS AND CHARACTERIZATION OF A MOLECULARLY IMPRINTED SORBENT ASSAY FOR ATRAZINE
MULDOON, MT
STANKER, LH
[J]. JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 1995, 43 (06) : 1424 - 1427

← 1 2 →