High resolution NMR techniques in catalysis

被引：26

作者：

Roe, DC ^{[1
]}

Kating, PM ^{[1
]}

Krusic, PJ ^{[1
]}

Smart, BE ^{[1
]}

机构：

[1] Dupont Co, Cent Res & Dev, Wilmington, DE 19880 USA

来源：

TOPICS IN CATALYSIS | 1998年 / 5卷 / 1-4期

关键词：

NMR; catalysis; high pressure; dynamic equilibria; magnetization transfer; sapphire tube; gas phase; kinetics;

D O I：

10.1023/A:1019133515789

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

High resolution NMR techniques are applicable to a variety of aspects of catalysis. Methods for studying homogeneously-catalyzed systems under high gas pressure are described along with approaches for obtaining mechanistic and dynamic information. Many of the same techniques may be applied to heterogeneous catalysis by following the reaction chemistry by gas phase NMR.

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页码：133 / 147

页数：15

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