An unusual photoreaction of 3,4-di-O-benzyl-hypericin

被引：5

作者：

Dax, TG ^{[1
]}

Falk, H ^{[1
]}

机构：

[1] Johannes Kepler Univ Linz, Inst Chem, A-4040 Linz, Austria

来源：

MONATSHEFTE FUR CHEMIE | 2000年 / 131卷 / 11期

关键词：

radical; hypericin; electron transfer;

D O I：

10.1007/s007060070031

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Upon irradiation of 3,4-di-O-benzyl-hypericin and proton sponge (bis-1,8-N,N-dimethylamino-naphthalene) in benzene solution, a stable radical ion pair formed which exhibited an intense absorption band around 800nm. This was advanced by UV/Vis, NMR, and ESR spectroscopy. In presence of oxygen, irradiation of this photoproduct led to an activated oxygen species which then attacked the proton sponge.

引用

页码：1217 / 1219

页数：3