Ultrafast third-order non-linear optical response of Diels-Alder adduct of fullerene C60 with a metallophthalocyanine

被引:36
作者
Huang, WT
Wang, SF
Liang, RS
Gong, QH [1 ]
Qiu, WF
Liu, YQ
Zhu, DB
机构
[1] Peking Univ, Natl Lab Mesoscop Phys, Beijing 100871, Peoples R China
[2] Peking Univ, Dept Phys, Beijing 100871, Peoples R China
[3] Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China
基金
中国国家自然科学基金;
关键词
D O I
10.1016/S0009-2614(00)00617-5
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The third-order optical non-linearity of a Diels-Alder adduct of fullerene C-60 With a copper phthalocyanine was investigated using the femtosecond time-resolved optical Ken gate method at 830 nm wavelength. Its non-resonant second-order hyperpolarizability was estimated to be 5.4 x 10(-31) esu. The non-linearity enhancement from the formation of the intramolecular charge-transfer complex is discussed. (C) 2000 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:354 / 358
页数:5
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